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Bio-inspired Catalysts

Language EnglishEnglish
Book Hardback
Book Bio-inspired Catalysts Thomas R. Ward
Libristo code: 01570676
With the aim of complementing well-established catalytic strategies for enantioselective catalysis,... Full description
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With the aim of complementing well-established catalytic strategies for enantioselective catalysis, the field of artificial metalloenzymes has attracted increasing interest in the past decade. Artificial metalloenzymes result from the incorporation of a catalytically active organometallic moiety within a macromolecular host. Localization of the competent metal is ensured either by covalent, dative or supramolecular anchoring in either DNA or a protein scaffold. The properties of the resulting hybrid catalysts combine attractive features of both homogeneous and enzymatic catalysis. In particular, the optimization of such systems can be achieved both by chemical and genetic means. The book, consisting of five chapters written by leading experts, critically summarizes the state of the art in enantioselective epoxidation, sulfoxidation, fluorination, hydrogenation, allylic alkylation, Diels-Alder cycloadditions as well as Michael additions catalyzed by artificial metalloenzymes. This timely review unambiguously demonstrates the compatibility and complementarity of organometallic and enzymatic catalysis.

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About the book

Full name Bio-inspired Catalysts
Language English
Binding Book - Hardback
Date of issue 2008
Number of pages 115
EAN 9783540877561
ISBN 3540877568
Libristo code 01570676
Weight 385
Dimensions 155 x 235 x 12
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